Applied BWR Radiochemistry:
Problem Assessment and Diagnosis
COURSE DESCRIPTION
The BWR Applied Radiochemistry course was developed by NWT to assist plant and
corporate chemistry personnel to:
- Assess methods used to control activity transport and buildup relative to meeting ALARA
objectives.
- Evaluate the various fuel activity release models and employ nuclide release
distributions to assess fuel failure modes and estimate the number of fuel defects.
- Assess the radiological impact of the fuel failure mode.
- Apply radiochemical measurements to quantify plant system performance.
This course has been developed by senior NWT personnel who have been
involved in nuclear power plant radioactivity measurements and activity transport control
programs for over 40 years. This experience is complemented by consideration of the
underlying physical and chemical principles in each area of instruction. Because of the
nature of the course, senior NWT personnel provide all instruction (see resumes).
The course is intended for BWR chemistry personnel involved in
radiochemical measurements, plant problem identification and diagnosis, and development of
corrective actions. It assumes that the student is familiar with the fundamentals of
radiochemistry and has a knowledge of the various plant systems. The course emphasis is on
calculations and solution of problems. Students are requested to bring actual plant
nuclide and chemistry data for problem input and discussion.
NWT BACKGROUND
NWT was formed in March 1974 to provide consulting and research and
development services to the electric utilities in the areas of water chemistry, water
treatment, corrosion, activity transport, radiochemistry and waste treatment. Since that
time, NWT has provided services to over 50 utilities in the U.S. and overseas with
emphasis on problem diagnosis. Extensive studies also have been performed on
state-of-the-art technologies for EPRI. NWT staff members also have participated in
industry committees chartered to develop chemistry guidelines for problem avoidance.
In the past few years, several training courses on the application of
problem assessment techniques employed by the NWT staff during routine consulting
activities have been developed. Utility plant and general office personnel have confirmed
that these classes have been of significant value in their efforts to optimize their
chemistry programs.
Based on the response to these courses. The radiochemistry course
outlined below was developed specifically to assist BWR personnel actively engaged in the
radiochemistry assessment area.
COURSE OUTLINE
I. Radiochemistry Fundamentals
A. Decay Relationships
1. Disintegration Rate
2. Relationship Between Half-Life and Decay Constant
3. Delay Corrections
4. Activity Units
5. Activity Buildup in Confined Volumes and
Demineralizer Beds
6. Decay during Sampling and Counting
7. Parent-Daughter Relations
a. Secular Equilibrium
b. Transient Equilibrium
c. No Equilibrium
B. Statistical Relations
1. Arithmetric Mean
2. Standard Deviation
3. Treatment of Errors for Normal Distribution
4. Normal or Gaussian Frequency Distribution Curve
a. Probability of Occurrence of
Deviations
5. Binomial and Poisson Distribution
6. Distribution of Counting Time
B. Radioactive Decay Modes
1. Beta Decay
a. ß- Decay
b. ß+ Decay
c. Electron Capture
2. Gamma Decay
a. Internal Transition
b. Internal Conversion
c. Characteristic X-rays and Auger
Electrons
3. Alpha Decay
D. Interaction of Radiation with Matter
1. Alpha Particles
2. Electrons
3. Electromagnetic Radiation (Photons)
a. Photoelectric Effect
b. Compton Scattering
c. Pair Production
4. Interaction of Neutrons with Matter
a. Types of Interactions
b. Cross-Sections
II. Activity Measurement Requirements
A. Standard Technical Specifications
B. Dose Equivalent Iodine
C. Gross Activity and E-Bar
D. Effluents
1. Gaseous
2. Liquid
3. Solid
E. Lower Level of Detection
III. I. BWR Activity Production and Transport
A. Sources of Activity
1. Activation Products
2. Fission Products
3. Transuranics
B. Activity Transport
1. Coolant and Impurity Activation Products
2. Activated Corrosion Products
a. Overview
b. Activation Equation
3. Radiation Buildup
a. Isotopes and Sources
b. Mechanisms of Transport and
Incorporation
4. Chemistry of Radioactivities in the BWR
a. Fission Product Chemistry
1) Fission Yields
b. Iodine Chemistry
1) Normal Chemistry
2) Shutdown Chemistry
3) Iodine Carryover
4) Iodine Volatility
c. Fluorine Chemistry
d. Fission Gas Chemistry
e. TRU Chemistry
f. Xenon Activity in Resin Beds
IV. I. I. BWR Fuel Status Assessment
A. Fission Product Formation and Release
B. Fission Product Distributions and Releases
1. Recoil
2. Diffusion
C. Characterization of Release Distribution
D. Fuel Burnup Effects
1. Offgas Distribution
2. Sr-92
3. Cs-137:Cs-134 Ratio
4. TRUs
E. Release Rate Calculations
1. Fission Gases
2. Iodine Isotopes
3. Iodine Spikes on Shutdown
F. INPO Fuel Reliability Index (FRI)
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LECTURERS
H. R. HELMHOLZ: Mr. Helmholz began his nuclear career in 1951 at
Hanford. He subsequently joined the Case Institute of Technology where he organized the
radiochemistry program and taught courses in nuclear chemistry. After several years at
KAPL and at NRTS at Idaho Falls, where he supervised the S5G chemistry laboratory, he
joined GE-Vallecitos and assumed responsibility for design and performance of chemical
test programs at operating BWRs. Since joining NWT in 1981, he has had responsibility for
numerous chemistry and radiochemistry projects including development of radioanalytical
procedures, plant chemistry reviews, training course development and presentation,
assessments of solid waste radioassay techniques, radwaste dose rate to curie conversions,
effluent monitoring, shutdown radiation measurements and failed fuel characterization.
G. F. PALINO: Dr. Palino has been a Principal Consultant with
NWT since 1979. From 1974 to 1979, he was associated with General Electric's Nuclear
Energy Division. Prior to joining GE, Dr. Palino taught chemistry, radio-chemistry and
engineering courses at San Jose State University, at Harvey Mudd College and at the
Federal University of Rio de Janiero. Since joining NWT, Dr. Palino's responsibilities
have included technical management of PWR primary and secondary system chemistry studies
and BWR radiation level assessment and control programs. He also has developed and
presented training courses for BWR and PWR chemistry staffs and has worked in the areas of
radwaste treatment, volume reduction, tracer calibration of flowmeters, condensate
demineralization and quantification of moisture carryover from PWR steam generators.
S. G. SAWOCHKA: Dr. Sawochka currently is President of NWT
Corporation. He has been involved with consulting and R&D projects in the fields of
water chemistry, water treatment, corrosion, and radwaste processing in BWR and PWR
systems for 50 years. He previously was Manager of Water Chemistry Development for General
Electric's BWR Systems Department. Dr. Sawochka has authored numerous publications in the
referenced areas and has been an active member of EPRI committees that have developed
guidelines for BWR and PWR chemistry control.
GENERAL INFORMATION
CLASS SCHEDULE: Classes will be held from 8:15 a.m. to 5:00 p.m.
Monday through Wednesday with one hour for lunch and 8:15 to noon on Thursday.
ENROLLMENT: Course enrollments are limited to 10. Reservations
can be made by phone 408-281-1100, fax 408-578-0790 or e-mail.
If you prefer, discuss your interests
with the Program Director.
FEE: The $1,500 course fee includes all course material, break
refreshments, lunches (3) and one scheduled dinner. Lodging and other meals are NOT
INCLUDED. A Certificate of Participation is provided to each participant.
REFUNDS AND CANCELLATIONS: If you cancel your registration at
least 3 weeks working days prior to the class start date, your fee minus a $50
administrative fee will be refunded. If you cancel less than 3 weeks prior, you
will be liable for the full fee. Unfortunately, there can be no exceptions to this policy.
Enrollment substitutions may be made at any time.
NWT Corporation reserves the right to cancel this class within two
weeks of start date if fewer than three students are enrolled.
LOCATION/LODGING: The class will be held at the NWT offices in
San Jose, California. Information on San Jose area hotels will be provided with enrollment
confirmation.
ON SITE TRAINING SESSIONS: For information about holding this
seminar at your site, employing plant specific data and system design information, please
contact the Program Director. Customized reduced length seminars also can be developed.
COMPLEMENTARY COURSES: The following NWT courses also are
intermittently offered at our San Jose offices:
PWR Operational Chemistry (4½ days)
BWR Operational Chemistry (4½ days)
Applied BWR Radiochemistry (3½ days)
Nuclear Fuel Status Assessment (2½ days)
These courses also can be customized for specific plants and held at
the plant site or corporate office. One or two day seminars on specific subjects or
directed at specific utility personnel also can be developed.
FOR FURTHER INFORMATION PLEASE CONTACT:
Dr. S.G. Sawochka (Program Director)
at (408) 281-1100, fax (408) 578-0790 or
e-mail: Sawochka@nwtcorp.com
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